- Auditioned for the role of "Sonny Monroe" on Sonny with a Chance (2009). She was beaten out by Demi Lovato who won the role.
- She is of German, English, Scottish, French, and Irish descent.
- She has a younger brother named Nick.
- She is the niece of American psychologist Christine Blasey Ford.
- Planning to attend USC.
- Mendler has long had interests outside of acting. She graduated from the University of Southern California in 2016 before she started working at the Massachusetts Institute of Technology (MIT) Media Lab in 2017. She enrolled in the graduate program in 2018, and then began a doctorate in philosophy at MIT in 2020. The next year, Mendler enrolled in Harvard Law School.
- Dated actor Shane Harper, who also played her onscreen boyfriend on Good Luck Charlie.
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